| publication name | Azeotropy in terpolymerisation reactions of tributyltin acrylate or methacrylate with itaconic acid or dimethylitaconate and N‐vinyl‐2‐pyrrolidone |
|---|---|
| Authors | MM Azab |
| year | 1993 |
| keywords | |
| journal | Polymer international |
| volume | 32 |
| issue | Not Available |
| pages | 283-288 |
| publisher | Not Available |
| Local/International | International |
| Paper Link | http://onlinelibrary.wiley.com/doi/10.1002/pi.4990320311/abstract |
| Full paper | download |
| Supplementary materials | Not Available |
Abstract
Ternary copolymerisations of tri-n-butyltin acrylate (TBTA) or tri-n-butyltin methacrylate (TBTMA) with itaconic acid (IA) or dimethylitaconate (DMI) and N-vinyl-2- pyrrolidone (NVP) were carried out in solution at 70 C in the presence of a free radical initiator. Experimental, terpolymerisation data agreed with calculations based on the Alfrey- Goldfinger equation. Ternary azeotropic compositions for TBTA-IA-NVP and TBTA-DMI-NVP systems were 52.60: 14.80: 32.60 and 56.60: 26.60: 16.80 mol%, respectively. Also ' ...