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Azeotropy in terpolymerisation reactions of tributyltin acrylate or methacrylate with itaconic acid or dimethylitaconate and N‐vinyl‐2‐pyrrolidone

Polymer international • 1993
العودة
معلومات البحث
المؤلفون MM Azab
الكلمات المفتاحية Not Available
المجلة العلمية Polymer international
الناشر Not Available
المجلد 32
العدد Not Available
الصفحات 283-288
publication.type International
رابط البحث Open Link
المواد المرفقة Not Available
الملخص
Ternary copolymerisations of tri-n-butyltin acrylate (TBTA) or tri-n-butyltin
methacrylate (TBTMA) with itaconic acid (IA) or dimethylitaconate (DMI) and N-vinyl-2-
pyrrolidone (NVP) were carried out in solution at 70 C in the presence of a free radical
initiator. Experimental, terpolymerisation data agreed with calculations based on the Alfrey-
Goldfinger equation. Ternary azeotropic compositions for TBTA-IA-NVP and TBTA-DMI-NVP
systems were 52.60: 14.80: 32.60 and 56.60: 26.60: 16.80 mol%, respectively. Also ' ...