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Kinetic analysis of thermal decomposition reactionsPart IV: Kinetics of formation of barium titanate in crystalline mixtures of barium carbonate and titanium dioxide

Thermochimica Acta • 1989
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Publication Information
Authors Zeinab A. Omran · Mahmoud A. Mousa · A. A. Abdel Fattah · El-Hussieny M. Diefallah
Keywords Not Available
Journal Thermochimica Acta
Publisher Not Available
Volume 145
Issue Not Available
Pages 271
publication.type International
Paper Link Not Available
Supplementary Materials Not Available
Abstract
The kinetics of formation of barium titanate from banum carbonate and titanium dioxide have been studied using isothermal and dynamic thermogravimetry techniques. Kinetic analysis of the isothermal data, considered from the point of view of various solid state reaction models, showed that the reaction is best described by the random nucleation Avrami equation Analysis of dynamic TG data, according to the integral methods of Coats and Redfern and of Ozawa, gave results which are not in agreement with each other or with the results obtained under isothermal conditions.