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Kinetic analysis of thermal decomposition reactionsPart IV: Kinetics of formation of barium titanate in crystalline mixtures of barium carbonate and titanium dioxide

Thermochimica Acta • 1989
العودة
معلومات البحث
المؤلفون Zeinab A. Omran · Mahmoud A. Mousa · A. A. Abdel Fattah · El-Hussieny M. Diefallah
الكلمات المفتاحية Not Available
المجلة العلمية Thermochimica Acta
الناشر Not Available
المجلد 145
العدد Not Available
الصفحات 271
publication.type International
رابط البحث Not Available
المواد المرفقة Not Available
الملخص
The kinetics of formation of barium titanate from banum carbonate and titanium dioxide have been studied using isothermal and dynamic thermogravimetry techniques. Kinetic analysis of the isothermal data, considered from the point of view of various solid state reaction models, showed that the reaction is best described by the random nucleation Avrami equation Analysis of dynamic TG data, according to the integral methods of Coats and Redfern and of Ozawa, gave results which are not in agreement with each other or with the results obtained under isothermal conditions.