The Cover Feature shows that pre‐activation‐based glycosylation separates donor activation and acceptor glycosylation into two distinct steps. As a result, unique stereochemical control can be achieved by judicious choices of protective groups, anomeric groups, additives, and solvents. Some highly challenging glycosyl linkages including β‐ mannosides and deoxy glycosides can now be prepared with high stereoselectivities. More information can be found in the Microreview by X. Huang et al