Staff Members - Benha University
Physico-chemical, mechanical, microstructure and durability characteristics of alkali activated Egyptian slag
Construction and Building Materials • 2014
Publication Information
Authors
Mohamed Heikal a,b,⇑, M.Y. Nassar a, G. El-Sayed a, S.M. Ibrahim a
Keywords
Alkaline activation
Electrical conductivity
Thermal analysis
Phase composition
Microstructure and durability
Journal
Construction and Building Materials
Publisher
Elseiver
Volume
Not Available
Issue
2014
Pages
60-72
publication.type
International
Paper Link
Open Link
Supplementary Materials
Not Available
Abstract
The aim of the present work is to study the characteristics of alkali activated Egyptian slag (GBFS) mixed
with different contents of Na2O and SiO2. The rate of the kinetic of activation of GBFS has been studied by
electrical conductivity, FTIR, DTA/TGA, XRD and SEM techniques. Electrical conductivity of alkali activated slag systems depends mainly on the binder composition, the activator type and its concentration.
The increase in alkali activator contents affected the location and intensities of the conductivity maximum. As the hydration time increases the amount of hydration products increase, hence the chemically
combined water and combined slag contents increase. SEM images showed the presence of (N,C)ASH gel
with low porosity. With the increase of the content of Na2O leads to form a denser closed microstructure,
leading to higher compressive strength values. The activated GBFS showed good durability in 5% MgSO4
or 5% MgCl2 solution, i.e., the compressive strength increased gradually with immersing time up to
180 days. The total chloride and total sulphate contents decrease with alkali activated GBFS due to the
forming hydrated products that fill some available open pores, thereby inhibiting Cl or SO4 2 ions
penetration; this effect leads to a decreased accessibility of Cl or SO4 2 ions towards the more dense with
low capillary pore structure. It can be concluded that alkali activated GBFS are more durable in 5% MgSO4
or 5% MgCl2 than OPC pastes.
with different contents of Na2O and SiO2. The rate of the kinetic of activation of GBFS has been studied by
electrical conductivity, FTIR, DTA/TGA, XRD and SEM techniques. Electrical conductivity of alkali activated slag systems depends mainly on the binder composition, the activator type and its concentration.
The increase in alkali activator contents affected the location and intensities of the conductivity maximum. As the hydration time increases the amount of hydration products increase, hence the chemically
combined water and combined slag contents increase. SEM images showed the presence of (N,C)ASH gel
with low porosity. With the increase of the content of Na2O leads to form a denser closed microstructure,
leading to higher compressive strength values. The activated GBFS showed good durability in 5% MgSO4
or 5% MgCl2 solution, i.e., the compressive strength increased gradually with immersing time up to
180 days. The total chloride and total sulphate contents decrease with alkali activated GBFS due to the
forming hydrated products that fill some available open pores, thereby inhibiting Cl or SO4 2 ions
penetration; this effect leads to a decreased accessibility of Cl or SO4 2 ions towards the more dense with
low capillary pore structure. It can be concluded that alkali activated GBFS are more durable in 5% MgSO4
or 5% MgCl2 than OPC pastes.