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publication name Negeada, Hydration characteristics of Prompt cement in the presence citric acid as retarder
Authors 86. Mohamed Heikal, H. El-Didamony, E.A. Kishar, M.A. Negeada
year 2015
keywords Prompt cement, Citric acid, Hydration characteristics, Retarder
journal Ceramics-Silikaty
volume 59
issue (1)
pages 17-23
publisher Institute of Chemical Technology, Prague
Local/International International
Paper Link Not Available
Full paper download
Supplementary materials Not Available
Abstract

The aim of the present work is to study the influence of citric acid (CA) as retarder on the properties of prompt cement pastes. The dosages of CA were 0.50, and 0.75, 1.00 and 1.25 mass% of prompt cement. The initial and final setting times, bulk density, compressive strength, total porosity, and hydration kinetics such as free lime, combined water contents and XRD for selected sample were investigated. The results obtained in this study showed that the addition of CA elongates the initial and final setting times and decreases the compressive strength and combined water contents, whereas, it increases the total porosity at all ages of hydration. CA retards the liberation of Ca(OH)2 of prompt pastes. The free lime contents of prompt cement pastes are slightly increased up to 28 days then sharply increased up to 90 days. Thus, it is suggested that citrate sorbed onto the clinker surface and formed a protective layer around the clinker grains retarding their dissolution. The sharp increase of compressive strength at later ages after 28 days up to 90 days. The presence of 0.75 mass% citric acid achieves the initial and final setting time of the prompt cement according to the ASTM specification.

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