| publication name | Organotin polymers—XVII. Azeotropy in terpolymerization reactions of tri‐n‐butyltin 4‐acryloyloxybenzoate wit alkyl acrylates or styrene and acrylonitrile |
|---|---|
| Authors | AA Mahmoud, AF Shaaban, MM Azab, NN Messiha |
| year | 1992 |
| keywords | |
| journal | Polymer international |
| volume | 28 |
| issue | Not Available |
| pages | 245-250 |
| publisher | Not Available |
| Local/International | International |
| Paper Link | http://onlinelibrary.wiley.com/doi/10.1002/pi.4990280311/abstract |
| Full paper | download |
| Supplementary materials | Not Available |
Abstract
Ternary copolymerizations of tri-n-butyltin 4-acryloyloxybenzoate (ABTB) with acrylonitrile (AN) and alkyl acrylates [methyl (MA), ethyl (EA) or butyl acrylate (BA)], methyl methacrylate (MMA) or styrene (ST) were carried out in solution at 70 C in the presence of free radical initiator. Experimental terpolymerization data agreed well with calculations based on the Alfrey-Goldfinger equation. The determination of unitary, binary and ternary azeotropies of various systems studied was easily handled by a computer program. The ...