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Organotin polymers—XVII. Azeotropy in terpolymerization reactions of tri‐n‐butyltin 4‐acryloyloxybenzoate wit alkyl acrylates or styrene and acrylonitrile

Polymer international • 1992
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Publication Information
Authors AA Mahmoud, AF Shaaban, MM Azab, NN Messiha
Keywords Not Available
Journal Polymer international
Publisher Not Available
Volume 28
Issue Not Available
Pages 245-250
publication.type International
Paper Link Open Link
Supplementary Materials Not Available
Abstract
Ternary copolymerizations of tri-n-butyltin 4-acryloyloxybenzoate (ABTB) with
acrylonitrile (AN) and alkyl acrylates [methyl (MA), ethyl (EA) or butyl acrylate (BA)], methyl
methacrylate (MMA) or styrene (ST) were carried out in solution at 70 C in the presence of
free radical initiator. Experimental terpolymerization data agreed well with calculations
based on the Alfrey-Goldfinger equation. The determination of unitary, binary and ternary
azeotropies of various systems studied was easily handled by a computer program. The ...