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Organotin polymers. XV. Azeotropy in terpolymerization reactions of tributyltin acrylate or methacrylate with itaconic acid or dimethylitaconate and acrylonitrile

Journal of applied polymer science • 1992
العودة
معلومات البحث
المؤلفون AA Mahmoud, AF Shaaban, MM Azab, NN Messiha
الكلمات المفتاحية Not Available
المجلة العلمية Journal of applied polymer science
الناشر Not Available
المجلد 44
العدد Not Available
الصفحات 1861-1867
publication.type International
رابط البحث Open Link
المواد المرفقة Not Available
الملخص
Ternary copolymerization of tri-n-butyltin acrylate (TBTA) or methylacrylate (TBTMA)
with itaconic acid (IA) or dimethyl itaconate (DMI) and acrylonitrile (AN) were carried out in
solution at 70 C in the presence of a free radical initiator. Experimental terpolymerization
data agreed well with calculations based on the Alfrey-Goldfinger equation. Ternary
azeotropic compositions for TBTA-IA-AN, TBTMA-IA-IA, and TBTMA-DMI-AN systems were
39.0: 26.1: 34.9, 51.7: 10.5: 37.8, and 00.3: 66.3: 33.4 mol%, respectively. Also,“pseudo- ...