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Azeotropy in terpolymerization of 2‐pyrimidyl acrylamide with different alkyl acrylates and acrylonitrile

Polymer international • 1994
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Publication Information
Authors SH El‐Hamouly, MM Azab
Keywords Not Available
Journal Polymer international
Publisher Not Available
Volume 34
Issue Not Available
Pages 203-211
publication.type International
Paper Link Open Link
Supplementary Materials Not Available
Abstract
2-Pyrimidyl acrylamide monomer (2PA) has been prepared by the reaction of 2-
amino pyrimidine with acrylolyl chloride in the presence of triethylamine as catalyst. Its
structure was confirmed by IR and 1 H NMR spectroscopy. Ternary copolymerizations of 2-
pyrimidyl acrylamide monomer (2PA) with methyl acrylate (MA), methyl methacrylate (MMA),
ethyl acrylate (EA), butyl acrylate (BuA) and acrylonitrile (AN) were carried out in THF at 65
C in the presence of a free radical initiator. Experimental terpolymerization data agree well ...