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Synthesis and binary copolymerizations of 2-pyrimidyl acrylamide with different alkyl acrylates, vinyl acetate and acrylonitrile

Polymer international • 1994
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Publication Information
Authors SH El Hamouly, MM Azab
Keywords Not Available
Journal Polymer international
Publisher Not Available
Volume 34
Issue Not Available
Pages 273-278
publication.type International
Paper Link Open Link
Supplementary Materials Not Available
Abstract
2-Pyrimidyl acrylamide (2PA) monomer was prepared by the reaction of 2-
aminopyrimidine with acryloyl chloride. Its structure was confirmed by IR, 1 H NMR, and MS
spectroscopy. Binary copolymerizations of this new monomer with methyl acrylate (MA),
ethyl acrylate (EA), butyl acrylate (BuA), methyl methacrylate (MMA), vinyl acetate (VA), and
acrylonitrile (AN) were performed in tetrahydrofuran, using 1 mol% azobisisobutyronitrile as
initiator at 65 C. N analysis and 1 H NMR spectroscopy were used to determine the ...