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Study of the copolymerization parameters of 2-thiozyl methacrylamide with different alkyl acrylates

Journal of Polymer Research • 2005
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Publication Information
Authors MM Azab
Keywords Not Available
Journal Journal of Polymer Research
Publisher Not Available
Volume 12
Issue Not Available
Pages 9-15
publication.type International
Paper Link Open Link
Supplementary Materials Not Available
Abstract
2-thiozyl methacrylamide (TMA) was synthesized by the reaction of 2-aminothiazole
with either methacryloyl chloride or methacrylic acid in the presence of triethylamine and N,
N′-dicyclohexylcarbodiimide, respectively. Binary copolymerization reactions of the
prepared monomer with methyl acrylate (MA), ethyl acrylate (EA), n-butyl acrylate (BA) and
tert-butylacrylate (t. BA) were performed in dimethylformamide at 65○ C using 1 mol%
azobisisobutyronitrile (AIBN) as initiator. The structure of the 2-thiozyl methacrylamide ...