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Copolymerization reactions of N-acryloyl-morpholine with some vinyl monomers.

Journal of Basic and Environmental Sciences • 2017
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Publication Information
Authors A.A.Khalil1, M.El-Hefnawy2, M.S.Behalo1, M.H.M.Ahmed1 and H.A.Elkhawaga
Keywords Copolymerization- Q and e values
Journal Journal of Basic and Environmental Sciences
Publisher BSW
Volume 4
Issue Not Available
Pages 268-276
publication.type International
Paper Link Not Available
Supplementary Materials Not Available
Abstract
N-Acryloylmorpholine was prepared by the reaction of acrylic acid with morpholine in the presence of N,N'-
dicyclohexylcarbodiimide. The monomer reactivity ratios for copolymerization reactions of N-acryloylmorpholine with
methyl acrylate, methyl methacrylate, styrene and vinyl acetate, respectively, in solution with azobisisobutyronitrile
(AIBN) as initiator were estimated by nitrogen analysis. The structure of the copolymers was investigated by IR and
1HNMR spectroscopy. The Q and e values for N-acryloylmorpholine were calculated.