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A Study of the Effect of Radiation And Doping on the Catalytic Activity of Some Oxides in the Decomposition of hydrogen Preoxide

Proc. Pakistan Acad. Sci • 1987
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Publication Information
Authors M.A,Mousa
Keywords Science
Journal Proc. Pakistan Acad. Sci
Publisher Not Available
Volume 24
Issue 4
Pages 327
publication.type International
Paper Link Not Available
Supplementary Materials Not Available
Abstract
The rates of hydrogen peroxide decomposition on pure, doped and gamma-irradiated oxides Chromium oxide, Cobalt oxide, Magnesium oxide Nickel oxide, Ferric oxide, Magnesium ferri oxide were measured in a temperature range of 25-40 degree centigrade. It was found that lattice defect induced by doping and gamma-irradiation affect the catalytic properties of the oxides, either by activation or deactivation. The correlation between the catalytic activity for the hydrogen peroxide decomposition and the electronic defects produced by doping and by gamma-irradiation in the oxides is dicussed. Generally, it was found that the p-type semiconductor oxides are more active towards hydrogen peroxide decomposition than the n-type semiconductor oxides.