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Corrosion inhibition of aluminum and aluminum silicon alloys in sodium hydroxide solutions by methyl cellulose

j.Mater.Enviro.sci • 2015
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Publication Information
Authors Salah Eid*, M. Abdallah, E. M. Kamar, A. Y. El-Etre
Keywords Not Available
Journal j.Mater.Enviro.sci
Publisher Not Available
Volume 6
Issue 3
Pages 892-901
publication.type International
Paper Link Not Available
Supplementary Materials Not Available
Abstract
Methyl cellulose was tested as inhibitor for corrosion of aluminum and aluminum silicon alloys in 0.1M NaOH solution.
The inhibition action of methyl cellulose was studied using potentiostatic polarization, electrochemical impedance
spectroscopy (EIS), cyclic voltammetry and potentiodynamic anodic polarization techniques. Effect of temperature on the
inhibition efficiency of studied and the values of activation thermodynamic parameters were calculated and explained. The
inhibition efficiency increases with increasing the concentration of methyl cellulose and decreases with increasing
temperature as well as Si content. This was attributed to a lower affinity of the inhibitor to adsorb on Si than on Al. The
inhibition action was explained on the basis of adsorption of methyl cellulose on the surface of Al or Al-Si alloys forming a
barrier of mass and charge transfer leading to protect the metal surface from the aggressive ions