Animal glue as green inhibitor for corrosion of aluminum and aluminum-silicon alloys in sodium hydroxide solutions
Journal of Molecular Liquids • 2016
Publication Information
Authors
M. Abdallah a,b,
⁎, E.M. Kamar a
, Salah Eid a
, A.Y. El-Etre a
Keywords
Not Available
Journal
Journal of Molecular Liquids
Publisher
elsevier
Volume
220
Issue
Not Available
Pages
755-761
publication.type
International
Paper Link
Not Available
Supplementary Materials
Not Available
Abstract
The inhibition effect of animal glue toward the corrosion of aluminum and two aluminum-silicon alloys in 0.1 M
NaOH solution was investigated using potentiostatic polarization, electrochemical impedance spectroscopy
(EIS), cyclic voltammetry and potentiodynamic anodic polarization techniques. The percentage inhibition effi-
ciency increases with increasing concentration of animal glue and decreases with increasing temperature as
well as Si content. The inhibiting effect of animal glue is due to the adsorption on the Al and two Al\Si alloys surface.
The adsorption process follows Langmuir isotherm. Polarization curves revealed that the studied inhibitor
acts as a mixed type inhibitor mainly cathodic. The effect of rising temperature on the inhibition efficiency was
studied and the values of activation thermodynamic parameters were computed and explained. It was found
that the animal glue provides a good protection to Al and Al\Si alloys against pitting corrosion by shifting the
pitting potential to more noble direction. Results obtained from all electrochemical techniques were consistent
with each other
NaOH solution was investigated using potentiostatic polarization, electrochemical impedance spectroscopy
(EIS), cyclic voltammetry and potentiodynamic anodic polarization techniques. The percentage inhibition effi-
ciency increases with increasing concentration of animal glue and decreases with increasing temperature as
well as Si content. The inhibiting effect of animal glue is due to the adsorption on the Al and two Al\Si alloys surface.
The adsorption process follows Langmuir isotherm. Polarization curves revealed that the studied inhibitor
acts as a mixed type inhibitor mainly cathodic. The effect of rising temperature on the inhibition efficiency was
studied and the values of activation thermodynamic parameters were computed and explained. It was found
that the animal glue provides a good protection to Al and Al\Si alloys against pitting corrosion by shifting the
pitting potential to more noble direction. Results obtained from all electrochemical techniques were consistent
with each other
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