Tensile deformation behavior and melting property of nano-sized ZnO particles reinforced Sn–3.0Ag–0.5Cu lead-free solder
Materials Science and Engineering A • 2014
Publication Information
Authors
A A El-Daly, T A Elmosalami, W. M. Desoky, M. G. El-Shaarawy, A. M. Abdraboh
Keywords
Not Available
Journal
Materials Science and Engineering A
Publisher
sciencedirect
Volume
618
Issue
Not Available
Pages
389-397
publication.type
International
Paper Link
Open Link
Supplementary Materials
Not Available
Abstract
In the present study, nano-sized ZnO particle-reinforced Sn–3.0Ag–0.5Cu (SAC305) composite solder was prepared by mechanically dispersing nano-particles into SAC305 solder at 900 1C for 2 h. The effects of ZnO addition on microstructure, melting behavior and corresponding mechanical properties of SAC305 solder were explored. Microstructure analysis revealed that the wurtzite ZnO particles were effective in reducing both the β-Sn grain size and spacing between Ag 3 Sn and Cu 6 Sn 5 particles. The refined microstructure, which resulted in a strong adsorption effect and high surface-free energy of ZnO nanoparticles, could obstruct the dislocation slipping, and thus provides classical dispersion strengthen-ing mechanism. This apparently enhances the yield stress (0.2%YS) and ultimate tensile strength (UTS) of SAC(305)–0.7%ZnO composite solder, whereas its ductility is lower than that of the SAC305 solder. In addition, ZnO particles keep the melting temperature of composite solder nearly at the SAC305 level although the pasty range is decreased. Empirical equations for 0.2% YS, UTS and elastic modulus E with the strain rate have been developed and the predicted tensile parameters for both solders are reasonably close to the present experimental data. & 2014 Elsevier B.V. All rights reserved.
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