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Novel insight into the behavior of carbon in the positive active material of the lead-acid battery

Diamond & Related Materials • 2023
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Publication Information
Authors Yasser S.H. Mahrous, Atef Y. Shenouda, Asmaa A.I. Ali, Mohamed . Barakat
Keywords Lead acid battery Positive active material Active carbon Activity enhancement
Journal Diamond & Related Materials
Publisher Elesiver
Volume 140
Issue Not Available
Pages 110498
publication.type International
Paper Link Not Available
Supplementary Materials Not Available
Abstract
Low-cost wood sawdust was investigated as a primary source for preparing active carbon to enhance the leadacid battery. This can give a scope to determine the suitable active functional groups required to develop that
battery. The fraction, − 1.0 mm in size, was a potential feedstock for the active carbon preparation using
phosphoric acid activation. The resulting precursor/H3PO4 mixture was pre-activated by solidifying at 150 ◦C for
2 h to eliminate water, leaving it a black adhesive solid. The hardened mixture was heated at 450 ◦C for an hour
at a rate of 10 ◦C min− 1 to complete the carbonization process. The produced active carbon was washed
repeatedly with deionized water, dried at 105 ◦C, and saved in plastic for analysis and use, it was called (oxidAC). The resulting active carbon has been identifed using different analytical methods such as; XRD, SEM, FTIR,
and BET. Results obtained revealed that the activated carbon additive, with a 2.5 % weight percentage, can
reduce effectively the accumulation of PbSO4 at the positive active material (PAM) of the lead-acid battery. The
role of the active carbon in improving the PAM behavior can be explained based on lead (II) ion adsorption on
the carbon surface.