Staff Members - Benha University
Synthesis and evaluation of poly (Indole/Thiophene) fused ring derivative for C- steel corrosion inhibitor in sulfuric acidic medium
Egyptian Journal of Chemistry • 2021
Publication Information
Authors
Asmaa A. I. Ali
, Rasha A. Baseer, Heba M. Abo-Salem, S.M. Syam
Keywords
Poly(2-amino-4(1-benzyl-1H-indol-3-yl)thiophene-3-carbonitrile); C- steel; Corrosion inhibition
Journal
Egyptian Journal of Chemistry
Publisher
Not Available
Volume
64
Issue
Not Available
Pages
6053 - 6066
publication.type
International
Paper Link
Open Link
Supplementary Materials
Not Available
Abstract
The current study aims to explore the anti-corrosion performance of Poly [2-amino-4(1-benzyl-1H-indol-3-yl) thiophene -3-
carbonitrile)] (PABITC) on C-steel in in 0.50 M H2SO4 using weight loss and potentiodynamic polarization measurements
(PDP).. PABITC was synthesized with different molecular weights 882, 921, 1388, 15788 g/mol using APS as an oxidizing
agent. The chemical structure of the polymer was characterized using H1NMR, DNMR, C13NMR, and FTIR spectroscopy .
Polarization results reveal that the synthesized polymer acts as a hybrid-type inhibitor. The adsorption of inhibitory atoms of
the polymer on the C- steel surface followed Langmuir isotherm. SEM and EDX assure the development of PABITC
adsorbed film on the C- steel surface. Quantum calculations were carried out to elucidate the reactive sites in PABITC. All the
results approve that PABITC makes a resistive layer to shrink the corrosion process.
carbonitrile)] (PABITC) on C-steel in in 0.50 M H2SO4 using weight loss and potentiodynamic polarization measurements
(PDP).. PABITC was synthesized with different molecular weights 882, 921, 1388, 15788 g/mol using APS as an oxidizing
agent. The chemical structure of the polymer was characterized using H1NMR, DNMR, C13NMR, and FTIR spectroscopy .
Polarization results reveal that the synthesized polymer acts as a hybrid-type inhibitor. The adsorption of inhibitory atoms of
the polymer on the C- steel surface followed Langmuir isotherm. SEM and EDX assure the development of PABITC
adsorbed film on the C- steel surface. Quantum calculations were carried out to elucidate the reactive sites in PABITC. All the
results approve that PABITC makes a resistive layer to shrink the corrosion process.