| publication name | Characterization of borate glasses doped with copper oxide for optical application |
|---|---|
| Authors | A Samir; Moukhtar A Hassan; A Abokhadra; L I Soliman; M. Elokr |
| year | 2019 |
| keywords | Alkali borate glasses; Optical properties; Bandpass filter; FTIR and ESR |
| journal | Optical and Quantum Electronics |
| volume | 51 |
| issue | Not Available |
| pages | 123 |
| publisher | Springer |
| Local/International | International |
| Paper Link | https://doi.org/10.1007/s11082-019-1819-7 |
| Full paper | download |
| Supplementary materials | Ahmed samir mahmoud ahmed_A. Samir 2019.pdf |
Abstract
Borate glasses having the formula x CuO–(50 −x)B2O3–30Na2O–20ZnO where x=0, 0.2, 0.5, 1, 4 and 7 mol% were investigated. The samples were prepared using the conventional melt-quenching technique. Physical properties were studied such as; X-ray difraction, FTIR spectra, and UV–visible transmission. The optical basicity, average electro negativity have been estimated. The estimated optical basicity, unlike electron negativity, exhibits an increase with increasing the CuO content. FTIR spectra show that BO4 ratio decreases with increasing CuO content leading to the formation of non-bridging oxygen’s. Some optical parameters such as the optical band gap, band tail width, crystal feld strength and the UV and NIR cut of were determined. The transmission spectrum revealed that the glassy samples containing high content of copper oxide behave as bandpass flters at higher content. The characterized parameters of these flters were found to be highly afected by the addition of CuO. In these glasses the broad absorption band observed at the wavelength 550 nm is characterized by the existence of Cu2+ ions. The optical absorption and ESR studies suggest that, the Cu-ions exist in the Cu2+ state and act as modifers by increasing the degree of disorder in the glass network. Hence, the present system behaves as a bandpass flter in the ultraviolet–visible region.