Optical, thermophysical and electrical characterization of PMMA (CdSe QDs) composite films
• 2014
Publication Information
Authors
N. M. Al-Hosiny & S. Abdallah & M. A. A. Moussa & Ali Badawi
Keywords
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publication.type
International
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Supplementary Materials
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Abstract
The concentration dependence of optical, thermophysical
and electrical behavior, based on poly-methyl
methacrylate filled with CdSe quantum dots (PMMA
(CdSe)) have been investigated. The PMMA(CdSe) concentration
was 0.001, 0.005, 0.01 and 0.05 wt.%. The composites
were prepared in the form of films by the solution
casting technique. The optical properties of PMMA(CdSe)
films have showed that, there is a red shift of the absorption
and photoluminescence (PL) after the QDs were added into
PMMA. The PL peak intensity of the composite was enhanced
by ≈ 2.5 times compared to the CdSe QDs. The
thermal conductivity (k) was obtained by measuring the
thermal diffusivity (α) and thermal effusivity (e) using the
photoacoustic (PA) technique. The composites exhibit≈
120 % improvement in k at 0.05 wt.% . Furthermore, the
dc electrical conductivity measurements of pure and doped
PMMA, showed that the obtained values were enhanced
about four orders of magnitude for the hig
and electrical behavior, based on poly-methyl
methacrylate filled with CdSe quantum dots (PMMA
(CdSe)) have been investigated. The PMMA(CdSe) concentration
was 0.001, 0.005, 0.01 and 0.05 wt.%. The composites
were prepared in the form of films by the solution
casting technique. The optical properties of PMMA(CdSe)
films have showed that, there is a red shift of the absorption
and photoluminescence (PL) after the QDs were added into
PMMA. The PL peak intensity of the composite was enhanced
by ≈ 2.5 times compared to the CdSe QDs. The
thermal conductivity (k) was obtained by measuring the
thermal diffusivity (α) and thermal effusivity (e) using the
photoacoustic (PA) technique. The composites exhibit≈
120 % improvement in k at 0.05 wt.% . Furthermore, the
dc electrical conductivity measurements of pure and doped
PMMA, showed that the obtained values were enhanced
about four orders of magnitude for the hig
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