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Optical, thermophysical and electrical characterization of PMMA (CdSe QDs) composite films

• 2014
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Publication Information
Authors N. M. Al-Hosiny & S. Abdallah & M. A. A. Moussa & Ali Badawi
Keywords Not Available
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Issue Not Available
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publication.type International
Paper Link Not Available
Supplementary Materials Not Available
Abstract
The concentration dependence of optical, thermophysical
and electrical behavior, based on poly-methyl
methacrylate filled with CdSe quantum dots (PMMA
(CdSe)) have been investigated. The PMMA(CdSe) concentration
was 0.001, 0.005, 0.01 and 0.05 wt.%. The composites
were prepared in the form of films by the solution
casting technique. The optical properties of PMMA(CdSe)
films have showed that, there is a red shift of the absorption
and photoluminescence (PL) after the QDs were added into
PMMA. The PL peak intensity of the composite was enhanced
by ≈ 2.5 times compared to the CdSe QDs. The
thermal conductivity (k) was obtained by measuring the
thermal diffusivity (α) and thermal effusivity (e) using the
photoacoustic (PA) technique. The composites exhibit≈
120 % improvement in k at 0.05 wt.% . Furthermore, the
dc electrical conductivity measurements of pure and doped
PMMA, showed that the obtained values were enhanced
about four orders of magnitude for the hig