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New equation of state for double Yukawa potential with application to Lennard–Jones fluids

Physics and Chemistry of Liquids • 2009
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Publication Information
Authors M Bahaa Khedr, SM Osman, MS Al Busaidi
Keywords Not Available
Journal Physics and Chemistry of Liquids
Publisher Taylor & Francis Group
Volume 47
Issue 3
Pages 237-249
publication.type International
Paper Link Not Available
Supplementary Materials Not Available
Abstract
We present a simple but accurate equation of state for double Yukawa fluids based on the
variational series mean spherical approximation (VSMSA). This allows us to investigate the
vapour–liquid equilibrium and its related thermodynamic properties. The comparisons with
computer simulation results of the Lennard–Jones (LJ) potential suggest the importance of
treating the attractive tail of the potential accurately via VSMSA. The estimated reduced
critical parameters TC= 1.342, ρ C= 0.29 and PC= 0.135 are in good agreement with other ...