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Expired Paracetamol as Corrosion Inhibitor for Low Carbon Steel in Sulfuric Acid. Electrochemical, Kinetics and Thermodynamics Investigation

Int. J. Electrochem. Sci. • 2021
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Publication Information
Authors Arej S Al-Gorair1* , M. Abdallah
Keywords Low carbon steel, Expired paracetamol, Polarization, Adsorption, Corrosion inhibitor.
Journal Int. J. Electrochem. Sci.
Publisher ESG
Volume 16
Issue 6
Pages Article ID: 210771
publication.type Local
Paper Link Open Link
Supplementary Materials Not Available
Abstract
Expired paracetamol is used as efficient inhibitor for the general and pitting corrosion of low carbon
steel (LCS) in 1.0 mol L−1 H2SO4 solution. Three electrochemical tests are used to measure the inhibition
efficacy. The inhibition efficacy increases with increasing the concentricity of the expired paracetamol
and with lowering temperature. The outcomes indicate the values of corrosion current density and
capacity of the double layer decrease while the charge transfer and the inhibition efficacy increase. The
values of pitting potential are moved to more positive trend. These outcomes emphasize the inhibitory
strength of expired paracetamol. The inhibition can be explicated in term of the spontaneous adsorption
of the complex formed between iron (II) ion and paracetamol on the surface LCS. The adsorption
followed Langmuir isotherm. The thermodynamics parameters for the activation and adsorption process
were assessed from the study of impact temperature