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Application of breakthrough curves to investigate the chemisorption of carbon monoxide and hydrogen gases on platinum/silica catalysts

Powder Technology 86 ( 1996) 239-242 • 1996
العودة
معلومات البحث
المؤلفون Mohamed Mokhtar Mohamed *, Mohamed Ashraf El-Erian
الكلمات المفتاحية Not Available
المجلة العلمية Powder Technology 86 ( 1996) 239-242
الناشر Not Available
المجلد Not Available
العدد Not Available
الصفحات Not Available
publication.type International
رابط البحث Not Available
المواد المرفقة Not Available
الملخص
A study has been made on the consecutive adsorption of CO/H2 gases on Pt/SiOz catalysts at 523 K using breakthrough measurements.
The criteria for dispersion, diffusion and change in the pore size is evaluated and discussed as well as the equilibrium kinetic curves, which
show to what extent the rates of sorption of one of the gases is affected by the presence of the other. The changes in average pore radii, surface
areas and pore volume were very well estimated and correlated well with the breakthrough data.