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Novel bioactive imidazole-containing polymeric surfactants as petroleum-collecting and dispersing agents: Synthesis and surface-active properties

Journal of Molecular Liquids • 2017
العودة
معلومات البحث
المؤلفون Ahmed H. Tantawy , Hany I. Mohameda, Ahmed A. Khalil, Kaouser A. Hebash , Mahmoud Z. Basyouni
الكلمات المفتاحية 1-Vinylimidazole Lauryl methacrylate Reactivity ratios Polymeric surfactants Petroleum-dispersing agents
المجلة العلمية Journal of Molecular Liquids
الناشر Elsevier
المجلد 236
العدد Not Available
الصفحات 376–384
publication.type International
رابط البحث Open Link
المواد المرفقة Not Available
الملخص
Novel series of imidazole-containing polymers and polymeric surfactants have been synthesized via an efficient
procedure. It included copolymerization of 1-vinyl-imidazole (VIM) with lauryl methacrylate (LMA) initiated by
benzoyl peroxide and the 1H NMRspectroscopic datawas utilized to estimate themonomer reactivity ratio. Conversion
of polymers to surfactants was achieved through quaternization of the imidazole nitrogenwith dimethyl
sulphate. Spectroscopic techniqueswere used to elucidate the chemical structures of all synthesized compounds.
The surface-active properties of polymeric surfactants beside their activities against various microbes were investigated.
In addition, petroleum-collecting and dispersing properties of surfactants in diluted and undiluted form
in varying waters were evaluated.