Novel bioactive imidazole-containing polymeric surfactants as petroleum-collecting and dispersing agents: Synthesis and surface-active properties
Journal of Molecular Liquids • 2017
معلومات البحث
المؤلفون
Ahmed H. Tantawy , Hany I. Mohameda, Ahmed A. Khalil, Kaouser A. Hebash , Mahmoud Z. Basyouni
الكلمات المفتاحية
1-Vinylimidazole
Lauryl methacrylate
Reactivity ratios
Polymeric surfactants
Petroleum-dispersing agents
المجلة العلمية
Journal of Molecular Liquids
الناشر
Elsevier
المجلد
236
العدد
Not Available
الصفحات
376–384
publication.type
International
رابط البحث
Open Link
المواد المرفقة
Not Available
الملخص
Novel series of imidazole-containing polymers and polymeric surfactants have been synthesized via an efficient
procedure. It included copolymerization of 1-vinyl-imidazole (VIM) with lauryl methacrylate (LMA) initiated by
benzoyl peroxide and the 1H NMRspectroscopic datawas utilized to estimate themonomer reactivity ratio. Conversion
of polymers to surfactants was achieved through quaternization of the imidazole nitrogenwith dimethyl
sulphate. Spectroscopic techniqueswere used to elucidate the chemical structures of all synthesized compounds.
The surface-active properties of polymeric surfactants beside their activities against various microbes were investigated.
In addition, petroleum-collecting and dispersing properties of surfactants in diluted and undiluted form
in varying waters were evaluated.
procedure. It included copolymerization of 1-vinyl-imidazole (VIM) with lauryl methacrylate (LMA) initiated by
benzoyl peroxide and the 1H NMRspectroscopic datawas utilized to estimate themonomer reactivity ratio. Conversion
of polymers to surfactants was achieved through quaternization of the imidazole nitrogenwith dimethyl
sulphate. Spectroscopic techniqueswere used to elucidate the chemical structures of all synthesized compounds.
The surface-active properties of polymeric surfactants beside their activities against various microbes were investigated.
In addition, petroleum-collecting and dispersing properties of surfactants in diluted and undiluted form
in varying waters were evaluated.
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