Montmorillonite incorporated Polymethylmethacrylate - matrix containing lithium trifluoromethanesulphonate (LTF) salt: Thermally stable polymer nano composite electrolyte for lithium - ion batteries application
Ionics • 2018
معلومات البحث
المؤلفون
Emad M. Masoud
الكلمات المفتاحية
Not Available
المجلة العلمية
Ionics
الناشر
Not Available
المجلد
Not Available
العدد
Not Available
الصفحات
Not Available
publication.type
International
رابط البحث
Not Available
المواد المرفقة
Not Available
الملخص
High and low content of montmorillonite incorporated polymethylmethacrylate matrix in the presence of lithiumtriflate salt was
investigated and studied. All samples were synthesized using the solution cast technique method. Different techniques (X-ray
diffraction, FT-IR, DSC, TG, and SEM) were used for structure characterization. X-ray diffraction (XRD) and Fourier transform
infrared (FT-IR) analyses confirmed the complete dissolution of lithiumtriflate salt and intercalation of montmorillonite within
the polymethylmethacrylate matrix. The different contents of montmorillonite showed different behaviors in both of structure and
properties. The sample containing the low content of 5 wt% montmorillonite showed the highest AC- conductivity value (σAc =
2.09 × 10−6 Ω−1.cm−1, at room temperature) with a big difference to the other ones. The same sample also showed a good thermal
stability (Td = 378 °C). Electrochemical stability of the same sample was also studied. All results were collected and discussed.
investigated and studied. All samples were synthesized using the solution cast technique method. Different techniques (X-ray
diffraction, FT-IR, DSC, TG, and SEM) were used for structure characterization. X-ray diffraction (XRD) and Fourier transform
infrared (FT-IR) analyses confirmed the complete dissolution of lithiumtriflate salt and intercalation of montmorillonite within
the polymethylmethacrylate matrix. The different contents of montmorillonite showed different behaviors in both of structure and
properties. The sample containing the low content of 5 wt% montmorillonite showed the highest AC- conductivity value (σAc =
2.09 × 10−6 Ω−1.cm−1, at room temperature) with a big difference to the other ones. The same sample also showed a good thermal
stability (Td = 378 °C). Electrochemical stability of the same sample was also studied. All results were collected and discussed.
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