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N-Sulfonylbenzotriazoles as Advantageous Reagents for C-Sulfonylation

J. Org. Chem. • 2005
العودة
معلومات البحث
المؤلفون Alan R. Katritzky,* Ashraf A. A. Abdel-Fattah, Anatoliy V. Vakulenko, and Hui Tao
الكلمات المفتاحية Not Available
المجلة العلمية J. Org. Chem.
الناشر American Chemical Society
المجلد 70
العدد Not Available
الصفحات 9191-9197
publication.type International
رابط البحث Not Available
المواد المرفقة Not Available
الملخص
Reactions of readily available N-(alkyl-, aryl-, and heteroarylsulfonyl)benzotriazoles 3a-h with
diverse nitriles, reactive heteroaromatics, alkylheteroaromatics, sulfones, and esters produced
R-cyanoalkyl sulfones 5a-i, sulfonylheteroaromatics 7a-e, R-(sulfonylalkyl)heterocycles 9a-f,
R-sulfonylalkyl sulfones 11a-g, and esters of R-sulfonyl acids 14a-c, respectively, in synthetically
useful to excellent yields. The results represent the first examples of the successful application of
sulfonylazoles for C-sulfonylation.